Product Details;
CasNo： 110-63-4
Molecular Formula： C4H10O2
Appearance： viscous colourless liquid
110-63-4 Properties
- Molecular Formula:C4H10O2
- Molecular Weight:90.1222
- Appearance/Colour:viscous colourless liquid
- Vapor Pressure:0.015mmHg at 25°C
- Melting Point:20 °C
- Refractive Index:n20/D 1.445(lit.)
- Boiling Point:227.999 °C at 760 mmHg
- PKA:14.73±0.10(Predicted)
- Flash Point:105.909 °C
- PSA：40.46000
- Density:1.006 g/cm3
- LogP:-0.24880
110-63-4 Usage
InChI:InChI=1/C4H10O2/c5-3-1-2-4-6/h5-6H,1-4H2
110-63-4 Relevant articles
Effect of boron content on 1,4-butanediol production by hydrogenation of succinic acid over Re-Ru/BMC (boron-modified mesoporous carbon) catalysts
Kang, Ki Hyuk,Han, Seung Ju,Lee, Jong Won,Kim, Tae Hyeop,Song, In Kyu
, p. 206 - 213 (2016)
Hydrogenation of γ-Butyrolactone to 1,4-Butanediol over CuCo/TiO2 Bimetallic Catalysts
Huang, Zhiwei,Barnett, Kevin J.,Chada, Joseph P.,Brentzel, Zachary J.,Xu, Zhuoran,Dumesic, James A.,Huber, George W.
, p. 8429 - 8440 (2017)
Extremely facile and selective nickel-catalyzed allyl ether cleavage
Taniguchi, Takahiko,Ogasawara, Kunio
, p. 1136 - 1137 (1998)
Thermodynamic equilibria between polyalcohols and cyclic ethers in high-temperature liquid water
Yamaguchi, Aritomo,Hiyoshi, Norihito,Sato, Osamu,Bando, Kyoko K.,Masuda, Yoshio,Shirai, Masayuki
, p. 2666 - 2668 (2009)
A temperature-controlled reversible ionic liquid - Water two phase - Single phase protocol for hydrogenation catalysis
Dyson,Ellis,Welton
, p. 705 - 708 (2001)
Comparison of Carbon-13 Nuclear Magnetic Resonance Methods for the Analysis of Multiple Partially Deuteriated Products from Catalytic Reactions: Heptan-1-ol and 2-Methylpropanol
MacDougall, Joanna K.,Simpson, Michael C.,Cole-Hamilton, David J.
, p. 3061 - 3066 (1994)
A Study of the Catalytic Deuteration of 1,4-Butynediol
Chickos, James S.,Uang, Jack Y.-J.,Keiderling, Tim A.
, p. 2594 - 2596 (1991)
High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects
Boogaerts, Ine T.I. F.,White, Daniel F. S.,Cole-Hamilton, David J.
, p. 2194 - 2196 (2010)
Continuous hydrogenation of 2-butyne-1,4-diol to 2-butene- and butane-1,4-diols
Rode,Tayade,Nadgeri,Jaganathan,Chaudhari
, p. 278 - 284 (2006)
A new carboxylesterase from Brevibacterium linens IFO 12171 responsible for the conversion of 1,4-butanediol diacrylate to 4-hydroxybutyl acrylate: Purification, characterization, gene cloning, and gene expression in Escherichia coli
Sakai, Yasuyoshi,Ishikawa, Junko,Fukasaka, Shunji,Yurimoto, Hiroya,Mitsui, Ryoji,Yanase, Hideshi,Kato, Nobuo
, p. 688 - 697 (1999)
Effect of Ethers on Reactions of Butylcoppers with α,β-Unsaturated Ketones in Toluene
Kingsbury, Celia L.,Smith, Robin A. J.
, p. 7637 - 7643 (1997)
A Novel and Unusual Reaction of Enol Ethers with Benzyltriethylammonium Borohydride and Chlorotrimethylsilane
Baskaran, S.,Chidambaram, N.,Narasimhan, N.,Chandrasekaran, S.
, p. 6371 - 6374 (1992)
A Schiff Base Modified Pd Catalyst for Selective Hydrogenation of 2-Butyne-1,4-diol to 2-Butene-1,4-diol
Li, Haomeng,Wang, Xinkui,Chen, Xiao,Li, Chuang,Wang, Min,Yi, Yanhui,Ji, Min,Wang, Huilong,Shao, Zhengfeng,Liang, Changhai
, p. 2150 - 2157 (2020)
Bimetallic Synergy Effects of Phyllosilicate-Derived NiCu@SiO2 Catalysts for 1,4-Butynediol Direct Hydrogenation to 1,4-Butanediol
Wang, Changzhen,Tian, Yani,Wu, Ruifang,Li, Haitao,Yao, Benzhen,Zhao, Yongxiang,Xiao, Tiancun
, p. 4777 - 4787 (2019)
Quantification of Interfacial pH Variation at Molecular Length Scales Using a Concurrent Non-Faradaic Reaction
Ryu, Jaeyune,Wuttig, Anna,Surendranath, Yogesh
, p. 9300 - 9304 (2018)
Modelling proposed intermediates in the hydrocarbonylation of alkenes catalysed by rhodium complexes of PBui3 and PPr i3
Cheliatsidou, Paraskevi,White, Daniel F. S.,Slawin, Alexandra M. Z.,Cole-Hamilton, David J.
, p. 2389 - 2394 (2008)
DIRECT SYNTHESIS OF 1,4-BUTANEDIOL FROM ALLYL ALCOHOL USING CARBON MONOXIDE AND WATER IN THE PRESENCE OF Rh6(CO)16-PROPANEDIAMINE SYSTEM
Kaneda, Kiyotomi,Imanaka, Toshinobu,Teranishi, Shiichiro
, p. 1465 - 1466 (1983)
An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate
Ravikumar,Chandrasekaran, Srinivasan
, p. 2973 - 2978 (1997)
Alkaline hydrolysis of oligomers of tartrate esters: Effect of a neighboring carboxyl on the reactivity of ester groups
Maniar,Kalonia,Simonelli
, p. 705 - 709 (1992)
New environmentally friendly catalysts containing Pd-interstitial carbon made from Pd-glucose precursors for ultraselective hydrogenations in the liquid phase
Chan, Chun Wong Aaron,Xie, Yaling,Cailuo, Nick,Yu, Kai Man Kerry,Cookson, James,Bishop, Peter,Tsang, Shik Chi
, p. 7971 - 7973 (2011)
Zirconium(IV) chloride catalyzed new and efficient protocol for the selective cleavage of p-methoxybenzyl ethers
Madhava Sharma, Gangavaram V.,Reddy, Ch. Govardhan,Krishna, Palakodety Radha
, p. 4574 - 4575 (2003)
Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity
Yin, Dongdong,Li, Chuang,Ren, Hangxing,Shekhah, Osama,Liu, Jinxuan,Liang, Changhai
, p. 1626 - 1633 (2017)
Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoO x/SiO2 catalyst
Wang, Zhiqiang,Li, Guangyi,Liu, Xiaoyan,Huang, Yanqiang,Wang, Aiqin,Chu, Wei,Wang, Xiaodong,Li, Ning
, p. 38 - 41 (2014)
Raney Ni-Si catalysts for selective hydrogenation of highly concentrated 2-butyne-1,4-diol to 2-butene-1,4-diol
Chen, Xiao,Zhang, Mingming,Yang, Kaixuan,Williams, Christopher T.,Liang, Changhai
, p. 1118 - 1126 (2014)
Kinetics and mechanism of tetrahydrofuran synthesis via 1,4-butanediol dehydration in high-temperature water
Hunter, Shawn E.,Ehrenberger, Carolyn E.,Savage, Phillip E.
, p. 6229 - 6239 (2006)
Liquid-phase catalytic hydrogenation of 2-butyne-1,4-diol to 1,4-butanediol at atmospheric pressure on suspended catalysts
Pyatnitsyna,El'Chaninov
, p. 394 - 397 (2013)
Analysis of drugs by pyrolysis. I. Selected ion monitoring combined with a pyrolysis method for the determination of carpronium chloride in biological samples.
Ohya,Sano
, p. 241 - 247 (1977)
Selective Hydrogenation of Cyclic Ester to α,ω-Diol Catalyzed by Cationic Ruthenium Complexes with Trialkylphosphine Ligands
Hara, Yoshinori,Inagaki, Hiroko,Nishimura, Sugio,Wada, Keisuke
, p. 1983 - 1986 (1992)
Tracking Electrical Fields at the Pt/H2O Interface during Hydrogen Catalysis
Ryu, Jaeyune,Surendranath, Yogesh
, p. AR (2019)
First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2
Khusainova,Khafizova,Tyumkina,Dzhemilev
, p. 1517 - 1523 (2015)
Converging conversion - using promiscuous biocatalysts for the cell-free synthesis of chemicals from heterogeneous biomass
Pick, André,Sieber, Volker,Sutiono, Samuel
, p. 3656 - 3663 (2021)
Catalytic hydrogenation of 2-butyne-1,4-diol to 2-butene-1,4-diol at atmospheric pressure in the liquid phase
Pyatnitsyna,El'chaninov,Savost'yanov
, p. 89 - 92 (2006)
Hydroboration Reaction and Mechanism of Carboxylic Acids using NaNH2(BH3)2, a Hydroboration Reagent with Reducing Capability between NaBH4and LiAlH4
Wang, Jin,Ju, Ming-Yue,Wang, Xinghua,Ma, Yan-Na,Wei, Donghui,Chen, Xuenian
, p. 5305 - 5316 (2021/04/12)
110-63-4 Process route
-
-
C36H60O30*C4H10O2
-
- 110-63-4
Butane-1,4-diol
-
- 10016-20-3
alpha cyclodextrin
Conditions
| Conditions | Yield |
|---|---|
|
In water; at 25 ℃; Equilibrium constant;
|
-
- 624-48-6
dimethyl cis-but-2-ene-1,4-dioate
-
- 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran
-
- 13436-45-8
2-methoxytetrahydrofuran
-
- 96-48-0
4-butanolide
-
- 71-23-8
propan-1-ol
-
-
1-methoxy-1,4-butanediol
-
- 64001-06-5
2-(4'-hydroxybutoxy)-tetrahydrofuran
-
-
4-hydroxy-butanoic acid 4-hydroxybutyl ester
-
- 110-63-4
Butane-1,4-diol
-
- 25714-71-0
4-hydroxybutyraldehyde
-
- 925-57-5
methyl 4-hydroxybutanoate
-
- 71-36-3
butan-1-ol
Conditions
| Conditions | Yield |
|---|---|
|
With hydrogen; at 190 ℃; under 46504.7 Torr; Gas phase;
|
79.1% 10.4% 5.3% |
110-63-4 Upstream products
-
1708-29-8
2,5-dihydrofuran
-
108-31-6
maleic anhydride
-
110-52-1
1,4-dibromo-butane
-
110-65-6
1,4-dihydroxybut-2-yne
110-63-4 Downstream products
-
13179-96-9
1,4-dimethoxybutane
-
5835-79-0
4-(1-hydroxypropyl)morpholine
-
53161-64-1
4,4'-butane-1,4-diyl-bis-morpholine
-
7191-20-0
2-phenyl-1,3,2-dioxaphosphepin-2-oxide
Relevant Products
-
4-Hydroxyphenethyl alcoholCAS NO.: 501-94-0CAS：501-94-0
-
(R)-(+)-1-(4-Methylphenyl)ethylamineCAS：4187-38-6
-
Benzene,1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis-CAS：1889-67-4
