12092-47-6

  • 产品名称:(1,5-环辛二烯)氯铑(I)二聚体
  • 分子式:C16H24Cl2Rh2
  • 技术指标:99%
  • 分子量:
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产品详情;

CasNo: 12092-47-6

分子式: C16H24Cl2Rh2

外观: colourless liquid

交货时间: In stock

生产能力: 10000|Gram|Day

技术指标: 99%

Melting point  243 °C (dec.)(lit.)
storage temp.  2-8°C
solubility  Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form  Crystals or Crystalline Powder
color  Orange to orange-brown
Sensitive  Air Sensitive & Hygroscopic
Stability: hygroscopic
NIST Chemistry Reference Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)
 
Safety Information
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
3
TSCA  Yes
HS Code  28439000
MSDS Information
Provider Language
Chloro(1,5-cyclooctadiene)rhodium(I) dimer English
SigmaAldrich English
ACROS English
ALFA English
 
Chloro(1,5-cyclooctadiene)rhodium(I) dimer Usage And Synthesis
Reaction
  1. Catalyst for coupling 1,3-dienes with activate methylene compounds.
  2. Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
  3. Rhodium source for asymmetric reductive aldol reaction.
  4. Cis-hydroboration of terminal alkynes.
  5. Rhodium source for [5 + 2] additions.
  6. Highly enantioselective for [2+2+2] carbocyclization reactions.
  7. Enantioselective hydroboration of cyclopropenes.

Chemical Properties orange crystals

 

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